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An Oxy-anion Accelerated [1,5]-o-Quinone Methide Shift During the Nucleophilic Epoxidation of Salicylfulvene
A new facet of nucleophilic fulvene epoxidations has been uncovered. 6-Arylfulvenes containing an ortho or para hydroxyl group react with basic hydrogen peroxide in an unusual manner; the epoxidation of the fulvene exocyclic double bond is followed by a phenoxide ion initiated epoxide ring opening t...
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| Publicado no: | European J Org Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7565285/ https://ncbi.nlm.nih.gov/pubmed/33071627 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201901620 |
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