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Substituents on Quinone Methides Strongly Modulate Formation and Stability of Their Nucleophilic Adducts
Electronic perturbation of quinone methides (QM) greatly influences their stability and in turn alters the kinetics and product profile of QM reaction with deoxynucleosides. Consistent with the electron deficient nature of this reactive intermediate, electron-donating substituents are stabilizing an...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2538442/ https://ncbi.nlm.nih.gov/pubmed/16953635 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja062948k |
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