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Cobalt-catalyzed deoxygenative triborylation of allylic ethers to access 1,1,3-triborylalkanes

Polyborylated organic compounds have been emerging as versatile building blocks in chemical synthesis. Here we report a selective cobalt-catalyzed deoxygenative 1,1,3-triborylation reaction of allylic ethers with pinacolborane to prepare 1,1,3-triborylalkane compounds. With naturally abundant and/or...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Teo, Wei Jie, Yang, Xiaoxu, Poon, Yeng Yeng, Ge, Shaozhong
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7562742/
https://ncbi.nlm.nih.gov/pubmed/33060600
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-19039-7
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