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Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes

Hydrosilylation of allenes is the addition of a hydrogen atom and a silyl group to a carbon–carbon double bond of an allene molecule and represents a straightforward and atom-economical approach to prepare synthetically versatile allylsilanes and vinylsilanes. However, this reaction generally produc...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Wang, Chao, Teo, Wei Jie, Ge, Shaozhong
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5741631/
https://ncbi.nlm.nih.gov/pubmed/29273720
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-017-02382-7
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