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Regioselective Allene Hydrosilylation Catalyzed by NHC Complexes of Nickel and Palladium
Regioselective methods for allene hydrosilylation have been developed, with regioselectivity being governed primarily by choice of metal. Alkenylsilanes are produced via nickel catalysis with larger N-heterocyclic carbene ligands, and allylsilanes are produced via palladium catalysis with smaller N-...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3838997/ https://ncbi.nlm.nih.gov/pubmed/24079389 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja407749w |
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