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Standard state free energies, not pK(a)s, are ideal for describing small molecule protonation and tautomeric states

The pK(a) is the standard measure used to describe the aqueous proton affinity of a compound, indicating the proton concentration (pH) at which two protonation states (e.g A(-) and AH) have equal free energy. However, compounds can have additional protonation states (e.g. AH(2)(+)), and may assume m...

Täydet tiedot

Tallennettuna:
Bibliografiset tiedot
Julkaisussa:J Comput Aided Mol Des
Päätekijät: Gunner, M R, Murakami, Taichi, Rustenburg, Ariën S., Işık, Mehtap, Chodera, John D.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2020
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC7556740/
https://ncbi.nlm.nih.gov/pubmed/32052350
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s10822-020-00280-7
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