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The key role of R–NHC coupling (R = C, H, heteroatom) and M–NHC bond cleavage in the evolution of M/NHC complexes and formation of catalytically active species
Complexes of metals with N-heterocyclic carbene ligands (M/NHC) are typically considered the systems of choice in homogeneous catalysis due to their stable metal–ligand framework. However, it becomes obvious that even metal species with a strong M–NHC bond can undergo evolution in catalytic systems,...
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| Publicado en: | Chem Sci |
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| Autores principales: | , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7553045/ https://ncbi.nlm.nih.gov/pubmed/33133486 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02629h |
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