Revealing the unusual role of bases in activation/deactivation of catalytic systems: O–NHC coupling in M/NHC catalysis

Numerous reactions are catalyzed by complexes of metals (M) with N-heterocyclic carbene (NHC) ligands, typically in the presence of oxygen bases, which significantly shape the performance. It is generally accepted that bases are required for either substrate activation (exemplified by transmetallati...

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Bibliografiset tiedot
Julkaisussa:Chem Sci
Päätekijät: Chernyshev, Victor M., Khazipov, Oleg V., Shevchenko, Maxim A., Chernenko, Andrey Yu., Astakhov, Alexander V., Eremin, Dmitry B., Pasyukov, Dmitry V., Kashin, Alexey S., Ananikov, Valentine P.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: Royal Society of Chemistry 2018
Aiheet:
Chemistry
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC6048739/
https://ncbi.nlm.nih.gov/pubmed/30061988
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01353e
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