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Revealing the unusual role of bases in activation/deactivation of catalytic systems: O–NHC coupling in M/NHC catalysis

Numerous reactions are catalyzed by complexes of metals (M) with N-heterocyclic carbene (NHC) ligands, typically in the presence of oxygen bases, which significantly shape the performance. It is generally accepted that bases are required for either substrate activation (exemplified by transmetallati...

Πλήρης περιγραφή

Αποθηκεύτηκε σε:
Λεπτομέρειες βιβλιογραφικής εγγραφής
Τόπος έκδοσης:Chem Sci
Κύριοι συγγραφείς: Chernyshev, Victor M., Khazipov, Oleg V., Shevchenko, Maxim A., Chernenko, Andrey Yu., Astakhov, Alexander V., Eremin, Dmitry B., Pasyukov, Dmitry V., Kashin, Alexey S., Ananikov, Valentine P.
Μορφή: Artigo
Γλώσσα:Inglês
Έκδοση: Royal Society of Chemistry 2018
Θέματα:
Διαθέσιμο Online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6048739/
https://ncbi.nlm.nih.gov/pubmed/30061988
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01353e
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