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Stereoselective α-Tertiary Alkylation of N-(Arylacetyl)oxazolidinones
A method has been developed for the α-tertiary alkylation of zirconium enolates of N-(arylacetyl)oxazolidinones. This reaction directly installs an all-carbon quaternary center vicinal to a benzylic tertiary carbon in a highly diastereoselective manner.
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| Publicado no: | Synlett |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7544157/ https://ncbi.nlm.nih.gov/pubmed/33041522 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0039-1690793 |
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