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The Origins of Stereoselectivity in the α-Alkylation of Chiral Hydrazones
Density functional theory calculations and experiment reveal the origin of stereoselectivity in the deprotonation–alkylation of chiral N-amino cyclic carbamate (ACC) hydrazones. When the ACC is a rigid, camphor-derived carbamate, the two conformations of the azaenolate intermediate differ in energy...
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| Asıl Yazarlar: | , , , , |
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| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2010
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3005816/ https://ncbi.nlm.nih.gov/pubmed/21070023 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo1019877 |
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