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The Origins of Stereoselectivity in the α-Alkylation of Chiral Hydrazones

Density functional theory calculations and experiment reveal the origin of stereoselectivity in the deprotonation–alkylation of chiral N-amino cyclic carbamate (ACC) hydrazones. When the ACC is a rigid, camphor-derived carbamate, the two conformations of the azaenolate intermediate differ in energy...

詳細記述

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書誌詳細
主要な著者: Krenske, Elizabeth H., Houk, K. N., Lim, Daniel, Wengryniuk, Sarah E., Coltart, Don M.
フォーマット: Artigo
言語:Inglês
出版事項: 2010
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3005816/
https://ncbi.nlm.nih.gov/pubmed/21070023
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo1019877
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