Nickel(IV)-Catalyzed C–H Trifluoromethylation of (Hetero)arenes

This Article describes the development of a stable Ni(IV) complex that mediates C(sp(2))–H trifluoromethylation reactions. This reactivity is first demonstrated stoichiometrically and then successfully translated to a Ni(IV)-catalyzed C–H trifluoromethylation of electron-rich arene and heteroarene s...

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Udgivet i:J Am Chem Soc
Main Authors: Meucci, Elizabeth A., Nguyen, Shay N., Camasso, Nicole M., Chong, Eugene, Ariafard, Alireza, Canty, Allan J., Sanford, Melanie S.
Format: Artigo
Sprog:Inglês
Udgivet: 2019
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7542544/
https://ncbi.nlm.nih.gov/pubmed/31379153
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b06383
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