Loading...

Diastereo‐ and Enantioselective Cross‐Couplings of Secondary Alkylcopper Reagents with 3‐Halogeno‐Unsaturated Carbonyl Derivatives

Chiral secondary alkylcopper reagents were prepared from the corresponding alkyl iodides with retention of configuration by an I/Li‐exchange using tBuLi (−100 °C, 1 min) followed by a transmetalation with CuBr⋅P(OEt)(3) (−100 °C, 20 s). These stereodefined secondary alkylcoppers underwent stereorete...

Fuld beskrivelse

Na minha lista:
Bibliografiske detaljer
Udgivet i:Chemistry
Main Authors: Kremsmair, Alexander, Skotnitzki, Juri, Knochel, Paul
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2020
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540566/
https://ncbi.nlm.nih.gov/pubmed/32557902
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002297
Tags: Tilføj Tag
Ingen Tags, Vær først til at tagge denne postø!