The Sphingosine and Acyl Chains of Ceramide [NS] Show Very Different Structure and Dynamics That Challenge Our Understanding of the Skin Barrier

The lipid phase of the uppermost human skin layer is thought to comprise highly rigid lipids in an orthorhombic phase state to protect the body against the environment. By synthesizing sphingosine‐d(28) deuterated N‐lignoceroyl‐d‐erythro‐sphingosine (ceramide [NS]), we compare the structure and dyna...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Engberg, Oskar, Kováčik, Andrej, Pullmannová, Petra, Juhaščik, Martin, Opálka, Lukáš, Huster, Daniel, Vávrová, Kateřina
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540555/
https://ncbi.nlm.nih.gov/pubmed/32515145
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202003375
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