Quantifying Through‐Space Substituent Effects

The description of substituents as electron donating or withdrawing leads to a perceived dominance of through‐bond influences. The situation is compounded by the challenge of separating through‐bond and through‐space contributions. Here, we probe the experimental significance of through‐space substi...

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Publicado en:Angew Chem Int Ed Engl
Autores principales: Burns, Rebecca J., Mati, Ioulia K., Muchowska, Kamila B., Adam, Catherine, Cockroft, Scott L.
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540488/
https://ncbi.nlm.nih.gov/pubmed/32542910
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202006943
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