α‐Amidoaldehydes as Substrates in Rhodium‐Catalyzed Intermolecular Alkyne Hydroacylation: The Synthesis of α‐Amidoketones

We show that readily available α‐amidoaldehydes are effective substrates for intermolecular Rh‐catalyzed alkyne hydroacylation reactions. The catalyst [Rh(dppe)(C(6)H(5)F)][BAr(F) (4)] provides good reactivity, and allows a broad range of aldehydes and alkynes to be used as substrates, delivering α‐...

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Vydáno v:Chemistry
Hlavní autoři: Pal, Ritashree, O'Brien, Sean C., Willis, Michael C.
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2020
Témata:
Communications
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540332/
https://ncbi.nlm.nih.gov/pubmed/32449532
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002478
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