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Regio- and Stereoselective Rhodium(II)-Catalyzed C–H Functionalization of Organosilanes by Donor/Acceptor Carbenes Derived from Aryldiazoacetates

The regioselective and enantioselective intermolecular sp(3) C–H functionalization of silicon-substituted alkanes with aryldiazoacetates was accomplished using the recently developed dirhodium catalyst Rh(2)(S-TPPTTL)(4). These reactions generate a diverse array of stereodefined substituted silacycl...

詳細記述

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書誌詳細
出版年:Org Lett
主要な著者: Garlets, Zachary J., Hicks, Elliot F., Fu, Jiantao, Voight, Eric A., Davies, Huw M. L.
フォーマット: Artigo
言語:Inglês
出版事項: 2019
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC7526748/
https://ncbi.nlm.nih.gov/pubmed/31184488
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b01833
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