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Regio- and Stereoselective Rhodium(II)-Catalyzed C–H Functionalization of Organosilanes by Donor/Acceptor Carbenes Derived from Aryldiazoacetates
The regioselective and enantioselective intermolecular sp(3) C–H functionalization of silicon-substituted alkanes with aryldiazoacetates was accomplished using the recently developed dirhodium catalyst Rh(2)(S-TPPTTL)(4). These reactions generate a diverse array of stereodefined substituted silacycl...
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| Publicado no: | Org Lett |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7526748/ https://ncbi.nlm.nih.gov/pubmed/31184488 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b01833 |
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