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Migratory functionalization of unactivated alkyl bromides for construction of all-carbon quaternary centers via transposed tert-C-radicals
Despite remarkable recent advances in transition-metal-catalyzed C(sp(3))−C cross-coupling reactions, there remain challenging bond formations. One class of such reactions include the formation of tertiary-C(sp(3))−C bonds, presumably due to unfavorable steric interactions and competing isomerizatio...
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| Veröffentlicht in: | Nat Commun |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Nature Publishing Group UK
2020
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7519689/ https://ncbi.nlm.nih.gov/pubmed/32978381 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-18658-4 |
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