Selective Enzymatic Oxidation of Silanes to Silanols

Compared to the biological world’s rich chemistry for functionalizing carbon, enzymatic transformations of the heavier homologue silicon are rare. We report that a wild-type cytochrome P450 monooxygenase (P450(BM3) from Bacillus megaterium, CYP102A1) has promiscuous activity for oxidation of hydrosi...

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Bibliografske podrobnosti
izdano v:Angew Chem Int Ed Engl
Main Authors: Bähr, Susanne, Brinkmann-Chen, Sabine, Garcia-Borràs, Marc, Roberts, John M., Katsoulis, Dimitris E., Houk, Kendall N., Arnold, Frances H.
Format: Artigo
Jezik:Inglês
Izdano: 2020
Teme:
Article
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7511438/
https://ncbi.nlm.nih.gov/pubmed/32212229
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202002861
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