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Generation of Magnesium Pentafluoropropen-2-olate from Hexafluoroisopropanol and Synthesis of 2,2,4,4,4-Pentafluoro-3,3-dihydroxyketones
2,2,4,4,4-Pentafluoro-3,3-dihydroxyketones are valuable precursors to difluoroenolates, following fragmentation during the release of trifluoroacetate; however, there are few synthetic strategies to prepare this unique class of compound. We have addressed this issue and report a mild, two-step synth...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7500852/ https://ncbi.nlm.nih.gov/pubmed/28107014 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b02863 |
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