Impact of Excited-State Antiaromaticity Relief in a Fundamental Benzene Photoreaction Leading to Substituted Bicyclo[3.1.0]hexenes

[Image: see text] Benzene exhibits a rich photochemistry which can provide access to complex molecular scaffolds that are difficult to access with reactions in the electronic ground state. While benzene is aromatic in its ground state, it is antiaromatic in its lowest ππ* excited states. Herein, we...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Slanina, Tomáš, Ayub, Rabia, Toldo, Josene, Sundell, Johan, Rabten, Wangchuk, Nicaso, Marco, Alabugin, Igor, Fdez. Galván, Ignacio, Gupta, Arvind K., Lindh, Roland, Orthaber, Andreas, Lewis, Richard J., Grönberg, Gunnar, Bergman, Joakim, Ottosson, Henrik
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7497645/
https://ncbi.nlm.nih.gov/pubmed/32456426
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b13769
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