A Predictive Model Towards Site‐Selective Metalations of Functionalized Heterocycles, Arenes, Olefins, and Alkanes using TMPZnCl⋅LiCl

The development of a predictive model towards site‐selective deprotometalation reactions using TMPZnCl⋅LiCl is reported (TMP=2,2,6,6‐tetramethylpiperidinyl). The pK (a) values of functionalized N‐, S‐, and O‐heterocycles, arenes, alkenes, or alkanes were calculated and compared to the experimental d...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Balkenhohl, Moritz, Jangra, Harish, Makarov, Ilya S., Yang, Shu‐Mei, Zipse, Hendrik, Knochel, Paul
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Research Articles
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7497272/
https://ncbi.nlm.nih.gov/pubmed/32400069
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202005372
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