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Preparation of Polyfunctional Biaryl Derivatives by Cyclolanthanation of 2‐Bromobiaryls and Heterocyclic Analogues Using nBu(2)LaCl⋅4 LiCl
Various aryl‐ and heteroaryl‐substituted 2‐bromobiaryls are converted to cyclometalated lanthanum intermediates by reaction with nBu(2)LaCl⋅4 LiCl. These resulting lanthanum heterocycles are key intermediates for the facile preparation of functionalized 2,2′‐diiodobiaryls, silafluorenes, fluoren‐9‐o...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Angew Chem Int Ed Engl |
|---|---|
| Prif Awduron: | , , , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
John Wiley and Sons Inc.
2019
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6856828/ https://ncbi.nlm.nih.gov/pubmed/31461206 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908046 |
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