N‐Heterocyclic Silylenes as Ligands in Transition Metal Carbonyl Chemistry: Nature of Their Bonding and Supposed Innocence

A study on the reactivity of the N‐heterocyclic silylene Dipp(2)NHSi (1,3‐bis(diisopropylphenyl)‐1,3‐diaza‐2‐silacyclopent‐4‐en‐2‐yliden) with the transition metal complexes [Ni(CO)(4)], [M(CO)(6)] (M=Cr, Mo, W), [Mn(CO)(5)(Br)] and [(η (5)‐C(5)H(5))Fe(CO)(2)(I)] is reported. We demonstrate that N‐h...

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Publicat a:Chemistry
Autors principals: Krahfuß, Mirjam J., Nitsch, Jörn, Bickelhaupt, F. Matthias, Marder, Todd B., Radius, Udo
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7497151/
https://ncbi.nlm.nih.gov/pubmed/32233000
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001062
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