Loading...

The Nature of Nonclassical Carbonyl Ligands Explained by Kohn–Sham Molecular Orbital Theory

When carbonyl ligands coordinate to transition metals, their bond distance either increases (classical) or decreases (nonclassical) with respect to the bond length in the isolated CO molecule. C−O expansion can easily be understood by π‐back‐donation, which results in a population of the CO's π...

Fuld beskrivelse

Na minha lista:
Bibliografiske detaljer
Udgivet i:Chemistry
Main Authors: van der Lubbe, Stephanie C. C., Vermeeren, Pascal, Fonseca Guerra, Célia, Bickelhaupt, F. Matthias
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2020
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756819/
https://ncbi.nlm.nih.gov/pubmed/33045113
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003768
Tags: Tilføj Tag
Ingen Tags, Vær først til at tagge denne postø!