Reversible N‐Heterocyclic Carbene‐Induced α‐H Abstraction in Tungsten(VI) Imido Dialkyl Dialkoxide Complexes

The first reversible N‐heterocyclic carbene (NHC) induced α‐H abstraction in tungsten(VI) imido‐dialkyl dialkoxide complexes is reported. Treatment of W(NAr)(CH(2)Ph)(2)(OtBu)(2) (Ar=2,6‐dichlorophenyl, 2,6‐dimethylphenyl, 2,6‐diisopropylphenyl) with different NHCs leads to the formation of complexe...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Musso, Janis V., Benedikter, Mathis J., Wang, Dongren, Frey, Wolfgang, Altmann, Hagen J., Buchmeiser, Michael R.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496809/
https://ncbi.nlm.nih.gov/pubmed/32202338
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000840
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