Reversible N‐Heterocyclic Carbene‐Induced α‐H Abstraction in Tungsten(VI) Imido Dialkyl Dialkoxide Complexes

The first reversible N‐heterocyclic carbene (NHC) induced α‐H abstraction in tungsten(VI) imido‐dialkyl dialkoxide complexes is reported. Treatment of W(NAr)(CH(2)Ph)(2)(OtBu)(2) (Ar=2,6‐dichlorophenyl, 2,6‐dimethylphenyl, 2,6‐diisopropylphenyl) with different NHCs leads to the formation of complexe...

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Sparad:
Bibliografiska uppgifter
I publikationen:Chemistry
Huvudupphovsmän: Musso, Janis V., Benedikter, Mathis J., Wang, Dongren, Frey, Wolfgang, Altmann, Hagen J., Buchmeiser, Michael R.
Materialtyp: Artigo
Språk:Inglês
Publicerad: John Wiley and Sons Inc. 2020
Ämnen:
Communications
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496809/
https://ncbi.nlm.nih.gov/pubmed/32202338
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000840
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