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Electroreductive Cobalt‐Catalyzed Carboxylation: Cross‐Electrophile Electrocoupling with Atmospheric CO(2)

The chemical use of CO(2) as an inexpensive, nontoxic C1 synthon is of utmost topical interest in the context of carbon capture and utilization (CCU). We present the merger of cobalt catalysis and electrochemical synthesis for mild catalytic carboxylations of allylic chlorides with CO(2). Styrylacet...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Ang, Nate W. J., Oliveira, João C. A., Ackermann, Lutz
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496797/
https://ncbi.nlm.nih.gov/pubmed/32329560
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202003218
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