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Electroreductive Cobalt‐Catalyzed Carboxylation: Cross‐Electrophile Electrocoupling with Atmospheric CO(2)

The chemical use of CO(2) as an inexpensive, nontoxic C1 synthon is of utmost topical interest in the context of carbon capture and utilization (CCU). We present the merger of cobalt catalysis and electrochemical synthesis for mild catalytic carboxylations of allylic chlorides with CO(2). Styrylacet...

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Publicado no:Angew Chem Int Ed Engl
Main Authors: Ang, Nate W. J., Oliveira, João C. A., Ackermann, Lutz
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496797/
https://ncbi.nlm.nih.gov/pubmed/32329560
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202003218
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