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Ir(III)‐Catalyzed Selective ortho‐Monoiodination of Benzoic Acids with Unbiased C−H Bonds

An iridium‐catalyzed selective ortho‐monoiodination of benzoic acids with two equivalent C−H bonds is presented. A wide range of electron‐rich and electron‐poor substrates undergo the reaction under mild conditions, with >20:1 mono/di selectivity. Importantly, the C−H iodination occurs selectivel...

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Détails bibliographiques
Publié dans:Chemistry
Auteurs principaux: Weis, Erik, Johansson, Magnus J., Martín‐Matute, Belén
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7496429/
https://ncbi.nlm.nih.gov/pubmed/32449557
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002204
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