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Zirconium‐Catalyzed Atom‐Economical Synthesis of 1,1‐Diborylalkanes from Terminal and Internal Alkenes
A general and atom‐economical synthesis of 1,1‐diborylalkanes from alkenes and a borane without the need for an additional H(2) acceptor is reported for the first time. The key to our success is the use of an earth‐abundant zirconium‐based catalyst, which allows a balance of self‐contradictory react...
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| Gepubliceerd in: | Angew Chem Int Ed Engl |
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| Hoofdauteurs: | , , , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
John Wiley and Sons Inc.
2020
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7496309/ https://ncbi.nlm.nih.gov/pubmed/32297413 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202002642 |
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