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Stereocontrolled Synthesis of Vinyl Boronates and Vinyl Silanes via An Atom-Economic Ruthenium-Catalyzed Alkene-Alkyne Coupling
The synthesis of vinyl boronates and vinyl silanes was achieved by employing a Ru-catalyzed alkene-alkyne coupling reaction of allyl boronates or allyl silanes with various alkynes. The double bond geometry in the generated vinyl boranes can be remotely controlled by the juxtaposing boron- and silic...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4715692/ https://ncbi.nlm.nih.gov/pubmed/26572804 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201509238 |
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