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Stereocontrolled Synthesis of Vinyl Boronates and Vinyl Silanes via An Atom-Economic Ruthenium-Catalyzed Alkene-Alkyne Coupling

The synthesis of vinyl boronates and vinyl silanes was achieved by employing a Ru-catalyzed alkene-alkyne coupling reaction of allyl boronates or allyl silanes with various alkynes. The double bond geometry in the generated vinyl boranes can be remotely controlled by the juxtaposing boron- and silic...

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Foilsithe in:Angew Chem Int Ed Engl
Main Authors: Trost, B. M., Koester, D. C., Herron, A. N.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2015
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4715692/
https://ncbi.nlm.nih.gov/pubmed/26572804
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201509238
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