Selective, High-Temperature O(2) Adsorption in Chemically Reduced, Redox-Active Iron-Pyrazolate Metal–Organic Frameworks

Developing O(2)-selective adsorbents that can produce high-purity oxygen from air remains a significant challenge. Here, we show that chemically reduced metal–organic framework materials of the type A(x)Fe(2)(bdp)(3) (A = Na(+), K(+); bdp(2−) = 1,4-benzenedipyrazolate; 0 < x ≤ 2), which feature c...

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Publicado en:J Am Chem Soc
Main Authors: Jaffe, Adam, Ziebel, Michael E., Halat, David M., Biggins, Naomi, Murphy, Ryan A., Chakarawet, Khetpakorn, Reimer, Jeffrey A., Long, Jeffrey R.
Formato: Artigo
Idioma:Inglês
Publicado: 2020
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC7484140/
https://ncbi.nlm.nih.gov/pubmed/32786654
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c06570
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