Negative cooperativity upon hydrogen bond-stabilized O(2) adsorption in a redox-active metal–organic framework

The design of stable adsorbents capable of selectively capturing dioxygen with a high reversible capacity is a crucial goal in functional materials development. Drawing inspiration from biological O(2) carriers, we demonstrate that coupling metal-based electron transfer with secondary coordination s...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Oktawiec, Julia, Jiang, Henry Z. H., Vitillo, Jenny G., Reed, Douglas A., Darago, Lucy E., Trump, Benjamin A., Bernales, Varinia, Li, Harriet, Colwell, Kristen A., Furukawa, Hiroyasu, Brown, Craig M., Gagliardi, Laura, Long, Jeffrey R.
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2020
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7303157/
https://ncbi.nlm.nih.gov/pubmed/32555184
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-16897-z
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