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Negative cooperativity upon hydrogen bond-stabilized O(2) adsorption in a redox-active metal–organic framework

The design of stable adsorbents capable of selectively capturing dioxygen with a high reversible capacity is a crucial goal in functional materials development. Drawing inspiration from biological O(2) carriers, we demonstrate that coupling metal-based electron transfer with secondary coordination s...

詳細記述

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書誌詳細
出版年:Nat Commun
主要な著者: Oktawiec, Julia, Jiang, Henry Z. H., Vitillo, Jenny G., Reed, Douglas A., Darago, Lucy E., Trump, Benjamin A., Bernales, Varinia, Li, Harriet, Colwell, Kristen A., Furukawa, Hiroyasu, Brown, Craig M., Gagliardi, Laura, Long, Jeffrey R.
フォーマット: Artigo
言語:Inglês
出版事項: Nature Publishing Group UK 2020
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC7303157/
https://ncbi.nlm.nih.gov/pubmed/32555184
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-16897-z
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