Pushing the Limits of Delta Bonding in Metal–Chromium Complexes with Redox Changes and Metal Swapping

Into the metalloligand Cr[N(o-(NCH(2)P((i)Pr)(2))-C(6)H(4))(3)] (1, CrL) was inserted a second chromium atom to generate the dichromium complex Cr(2)L (2), which is a homobimetallic analogue of the known MCrL complexes, where M is manganese (3) or iron (4). The cationic and anionic counterparts, [MC...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Eisenhart, Reed J., Rudd, P. Alex, Planas, Nora, Boyce, David W., Carlson, Rebecca K., Tolman, William B., Bill, Eckhard, Gagliardi, Laura, Lu, Connie C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5960016/
https://ncbi.nlm.nih.gov/pubmed/26168331
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b01163
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