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Mechanism Underlying Anti-Markovnikov Addition in the Reaction of Pentalenene Synthase
Most terpene synthase reactions follow Markovnikov rules for formation of high energy carbenium ion intermediates. However, there are notable exceptions. For example, pentalenene synthase (PS) undergoes an initial anti-Markovnikov cyclization reaction followed by a 1,2-hydride shift to form an inter...
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| Publicado no: | Biochemistry |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7484107/ https://ncbi.nlm.nih.gov/pubmed/32786410 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.0c00518 |
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