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Anomalous chemically induced electron spin polarization in proton-coupled electron transfer reactions: insight into radical pair dynamics

Time-resolved electron paramagnetic resonance (TREPR) spectroscopy has been used to study the proton coupled electron transfer (PCET) reaction between a ruthenium complex (Ru(bpz)(bpy)(2)) and several substituted hydroquinones (HQ). After excitation at 355 nm, the HQ moiety forms a strong hydrogen b...

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Foilsithe in:Chem Sci
Main Authors: Brugh, Alexander M., Forbes, Malcolm D. E.
Formáid: Artigo
Teanga:Inglês
Foilsithe: Royal Society of Chemistry 2020
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7480077/
https://ncbi.nlm.nih.gov/pubmed/32953022
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02691c
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