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Diastereo- and Enantioselective 1,4-Difunctionalization of Borylenynes by Catalytic Conjunctive Cross-Coupling

Enantioselective conjunctive cross-coupling of enyne-derived boronate complexes occurs with 1,4 addition of the electrophile and migrating group across the π system. This reaction pathway furnishes α-boryl allenes as the reaction product. In the presence of a chiral catalyst, both the central and ax...

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Bibliografske podrobnosti
izdano v:Angew Chem Int Ed Engl
Main Authors: Law, Chunyin, Kativhu, Elton, Wang, Johnny, Morken, James P.
Format: Artigo
Jezik:Inglês
Izdano: 2020
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7473481/
https://ncbi.nlm.nih.gov/pubmed/32212403
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202001580
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