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Computational Study on the Boundary Between the Concerted and Stepwise Mechanism of Bimolecular S(N)Ar Reactions
[Image: see text] The text-book mechanism of bimolecular nucleophilic aromatic substitutions (S(N)Ar) reactions is a stepwise process that proceeds via a so-called Meisenheimer intermediate. Only recently the alternative, concerted version of this mechanism has gained acceptance as more and more exa...
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| Veröffentlicht in: | J Am Chem Soc |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
American Chemical
Society
2020
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| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7472429/ https://ncbi.nlm.nih.gov/pubmed/32786763 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c01975 |
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