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Computational Study on the Boundary Between the Concerted and Stepwise Mechanism of Bimolecular S(N)Ar Reactions

[Image: see text] The text-book mechanism of bimolecular nucleophilic aromatic substitutions (S(N)Ar) reactions is a stepwise process that proceeds via a so-called Meisenheimer intermediate. Only recently the alternative, concerted version of this mechanism has gained acceptance as more and more exa...

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書目詳細資料
發表在:J Am Chem Soc
Main Authors: Rohrbach, Simon, Murphy, John A., Tuttle, Tell
格式: Artigo
語言:Inglês
出版: American Chemical Society 2020
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC7472429/
https://ncbi.nlm.nih.gov/pubmed/32786763
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c01975
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