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Impact of the Carbene Derivative Charge on the Decomposition Rates of Hoveyda–Grubbs-like Metathesis Catalysts

[Image: see text] Hoveyda–Grubbs metathesis catalysts undergo a relatively fast decomposition in the presence of olefins. Using a computational density functional theory approach, we show that positively charged derivatives of N-heterocyclic carbenes have little impact on the degradation/deactivatio...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:J Phys Chem A
Prif Awduron: Jawiczuk, Magdalena, Marczyk, Anna, Młodzikowska-Pieńko, Katarzyna, Trzaskowski, Bartosz
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: American Chemical Society 2020
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC7460089/
https://ncbi.nlm.nih.gov/pubmed/32639748
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.0c03096
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