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Impact of the Carbene Derivative Charge on the Decomposition Rates of Hoveyda–Grubbs-like Metathesis Catalysts
[Image: see text] Hoveyda–Grubbs metathesis catalysts undergo a relatively fast decomposition in the presence of olefins. Using a computational density functional theory approach, we show that positively charged derivatives of N-heterocyclic carbenes have little impact on the degradation/deactivatio...
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| Gepubliceerd in: | J Phys Chem A |
|---|---|
| Hoofdauteurs: | , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
American Chemical
Society
2020
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| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7460089/ https://ncbi.nlm.nih.gov/pubmed/32639748 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.0c03096 |
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