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CO(2) Capture by 2-(Methylamino)pyridine Ligated Aluminum Alkyl Complexes
A set of novel, easily synthesized aluminum complexes, Al[κ(2)-N,N-2-(methylamino)pyridine](2)R (R = Et, iBu) are reported. When subjected to 1 atm of CO(2) pressure, each hemilabile pyridine arm dissociates and facilitates cooperative activation of the CO(2) substrate reminiscent of a Frustrated Le...
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| Published in: | Eur J Inorg Chem |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2020
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7457790/ https://ncbi.nlm.nih.gov/pubmed/32879618 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.202000437 |
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