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CO(2) Capture by 2-(Methylamino)pyridine Ligated Aluminum Alkyl Complexes

A set of novel, easily synthesized aluminum complexes, Al[κ(2)-N,N-2-(methylamino)pyridine](2)R (R = Et, iBu) are reported. When subjected to 1 atm of CO(2) pressure, each hemilabile pyridine arm dissociates and facilitates cooperative activation of the CO(2) substrate reminiscent of a Frustrated Le...

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Bibliographic Details
Published in:Eur J Inorg Chem
Main Authors: Yokley, Timothy W., Tupkar, Hrishikesh, Schley, Nathan D., DeYonker, Nathan J., Brewster, Timothy P.
Format: Artigo
Language:Inglês
Published: 2020
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7457790/
https://ncbi.nlm.nih.gov/pubmed/32879618
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.202000437
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