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Ligand-based Photooxidations of Dithiomaltolato Complexes of Ru(II) and Zn(II): Photolytic CH Activation and Evidence of Singlet Oxygen Generation and Quenching
The complex [Ru(bpy)(2)(ttma)](+) (bpy = 2,2′-bipyridine; ttma = 3-hydroxy-2-methyl-thiopyran-4-thionate, 1, has previously been shown to undergo an unusual C-H activation of the dithiomaltolato ligand upon outer-sphere oxidation. The reaction generated alcohol and aldehyde products 2 and 3 from C-H...
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| Udgivet i: | Dalton Trans |
|---|---|
| Main Authors: | , , , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2014
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7455015/ https://ncbi.nlm.nih.gov/pubmed/24915154 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4dt00961d |
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