Ligand-based Photooxidations of Dithiomaltolato Complexes of Ru(II) and Zn(II): Photolytic CH Activation and Evidence of Singlet Oxygen Generation and Quenching

The complex [Ru(bpy)(2)(ttma)](+) (bpy = 2,2′-bipyridine; ttma = 3-hydroxy-2-methyl-thiopyran-4-thionate, 1, has previously been shown to undergo an unusual C-H activation of the dithiomaltolato ligand upon outer-sphere oxidation. The reaction generated alcohol and aldehyde products 2 and 3 from C-H...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Dalton Trans
Prif Awduron: Bruner, Britain, Walker, Malin Backlund, Ghimire, Mukunda M., Zhang, Dong, Selke, Matthias, Klausmeyer, Kevin, Omary, Mohammad A., Farmer, Patrick J.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2014
Pynciau:
Article
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC7455015/
https://ncbi.nlm.nih.gov/pubmed/24915154
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4dt00961d
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