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Visible-Light-Induced Palladium-Catalyzed Generation of Aryl Radicals from Aryl Triflates
A mild visible-light-induced Pd-catalyzed intramolecular C–H arylation of amides is reported. The method operates by cleavage of a C(sp(2))–O bond, leading to hybrid aryl Pd-radical intermediates. The following 1,5-hydrogen atom translocation, intramolecular cyclization, and rearomatization steps le...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7446712/ https://ncbi.nlm.nih.gov/pubmed/32155303 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201915962 |
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