Hydrogen Bonding Phase-Transfer Catalysis with Ionic Reactants: Enantioselective Synthesis of γ-Fluoroamines

[Image: see text] Ammonium salts are used as phase-transfer catalysts for fluorination with alkali metal fluorides. We now demonstrate that these organic salts, specifically azetidinium triflates, are suitable substrates for enantioselective ring opening with CsF and a chiral bis-urea catalyst. This...

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發表在:J Am Chem Soc
Main Authors: Roagna, Giulia, Ascough, David M. H., Ibba, Francesco, Vicini, Anna Chiara, Fontana, Alberto, Christensen, Kirsten E., Peschiulli, Aldo, Oehlrich, Daniel, Misale, Antonio, Trabanco, Andrés A., Paton, Robert S., Pupo, Gabriele, Gouverneur, Véronique
格式: Artigo
語言:Inglês
出版: American Chemical Society 2020
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC7441491/
https://ncbi.nlm.nih.gov/pubmed/32608977
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c05131
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