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Radical SAM Enzyme HydE Generates Adenosylated Fe(I) Intermediates En Route to the [FeFe]-Hydrogenase Catalytic H‑Cluster
The H-cluster of [FeFe]-hydrogenase consists of a [4Fe–4S](H)-subcluster linked by a cysteinyl bridge to a unique organometallic [2Fe](H)-subcluster assigned as the site of interconversion between protons and molecular hydrogen. This [2Fe](H)-subcluster is assembled by a set of Fe–S maturase enzymes...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7440672/ https://ncbi.nlm.nih.gov/pubmed/32434327 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c03802 |
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