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Synthesis of Highly Oxygenated Bicyclic Carbasugars. Remarkable Difference in the Reactivity of the d-gluco and d-xylo- Derived Trienes

2,3,4-Tri-O-benzyl-D-xylopyranose was used as a starting material in the preparation of the corresponding triene, which underwent smooth cyclization to a polyhydroxylated hydrindane, as a single diastereoisomer. The analogous triene prepared from D-glucose did not undergo any cyclization even under...

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Dettagli Bibliografici
Pubblicato in:Molecules
Autori principali: Witkowski, Grzegorz, Potopnyk, Mykhaylo A., Tiara, Karolina, Osuch-Kwiatkowska, Anna, Jarosz, Sławomir
Natura: Artigo
Lingua:Inglês
Pubblicazione: MDPI 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7436230/
https://ncbi.nlm.nih.gov/pubmed/32722067
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25153357
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