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Synthesis of a sucrose-based macrocycle with unsymmetrical monosaccharides "arms"
An efficient methodology for the selective substitution of both terminal positions (C6 and C6’) in 1’,2,3,3’,4,4’-hexa-O-benzylsucrose with different unsaturated monosaccharide units is presented. Such a highly functionalized intermediate was cyclized under RCM conditions to afford a macrocyclic der...
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| Publicado en: | Beilstein J Org Chem |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Beilstein-Institut
2018
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5870162/ https://ncbi.nlm.nih.gov/pubmed/29623125 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.14.50 |
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